敞开酸溶-电感耦合等离子体光谱法测定钨矿石和钼矿石中微量元素   总被引：4，自引：4，他引：0  

黄光明  蔡玉曼  王冰  乔爱香  高孝礼  江冶 《岩矿测试》2013,32(3):431-435

钨矿石和钼矿石具有丰富的共生或伴生元素,检测共生或伴生元素的含量有利于矿产资源的综合利用.在国家标准方法中钨矿石和钼矿石的共生或伴生元素含量是按元素分别检测,效率很低.本文在敞开体系中用盐酸+硝酸+氢氟酸+高氯酸消解样品,以7％盐酸溶解盐类,电感耦合等离子体发射光谱同时测定钨矿石和钼矿石中铋、钴、铜、锂、镍、磷、铅、锶、钒、锌等10种微量元素.选定了各元素的分析谱线和光谱级次,采用离峰背景校正法消除背景干扰,干扰元素校正系数法消除元素间的谱线重叠干扰.方法检出限为1.43 ～ 18.8 μg/g,加标回收率为90％ ～ 110％.经钨矿石和钼矿石标准物质分析验证,测定结果与标准值基本吻合,方法精密度(RSD,n=10)小于8％.该方法克服了碱熔引入大量碱金属元素以及可能引入杂质的缺陷,又不用处理钨酸和钼酸沉淀,能快速测定钨矿石和钼矿石中微量共生或伴生元素.  相似文献   

A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS     

Sarah Gilbert  Leonid Danyushevsky  Philip Robinson  Cora Wohlgemuth‐Ueberwasser  Norman Pearson  Dany Savard  Marc Norman  Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.  相似文献   

完整性检测在冲（钻）孔灌注桩的合理应用     

蔡洪美 《福建地质》2009,28(2):136-142

通过对3个工程实例的分析,发现在低应变法和声波透射法对冲（钻）孔灌注桩各种缺陷检测中存在不同结果,提出了各种完整性检测的适用范围,使冲（钻）孔灌注桩桩基检测方案和检测工作更加完善、合理。  相似文献   

东胜区污染状况分析   总被引：1，自引：0，他引：1  

侯慧萍  刘克利  金柏青  孙红斌 《内蒙古气象》2009,(2):20-22

文章利用东胜区主要污染源排放情况以及2005年9月1日-2007年8月31日每日SO2、NO2、PM10浓度监测值和2005-2007年SO2、NO2、PM10平均值,分析了东胜区主要污染类型、污染物来源以及东胜区近3年SO2、NO2、PM10监测值日、月、季、年分布特征和变化规律;提出了消减大气污染物排放的对策。  相似文献   

浅谈北京规划市区1:500地形图数字化测绘     

张立军 《北京测绘》2012,(6):95-98

地形图为国民经济建设和社会各行各业的发展提供测绘保障,它是城市规划设计、市政工程建设、工业与民用建筑、土地开发利用、防灾减灾等各方面的基础数据之一。本文结合北京城市基础测绘工作,以《BSCS G2000》测图软件为例,简述大比例尺数字化地形图的作业流程,地形要素取舍及检查验收工作。  相似文献   

诸广花岗岩体放射性水异常的某些特征     

吴敬炳 《华东地质学院学报》1986,(2)

本文以寻找铀矿为目的,在该岩体140Km~2面积上进行水化学普查,发现水异常370个,其特征为:若异常多且成片出现,则预示着有单个矿体规模不大的矿体群存在;条带状展布的水异常预示着存在方向相同的矿化带;阻水阻气构造带近旁之异常预示水源上方存在矿化;水温偏高之水异常与矿化关系密切;与矿化有关的多为铀—氡混合异常;大构造处之水异常并不表示此构造存在矿化,面往往是在其附近次一级构造中成矿.  相似文献   

对"工业指标"制定及应用的探讨          下载免费PDF全文

李会民 《地质找矿论丛》2003,18(Z1):108-109

工业指标的"多年一贯制"不利于合理充分地利用矿产资源,文章提出适合经济规律的工业指标制定办法,建议地质技术人员按照矿山年总成本和矿产品市场价格及时修正工业指标,以便使项目上马决策趋于正确.  相似文献   

北方农牧交错带退耕还林还草经济政策优化调控   总被引：4，自引：0，他引：4  

甘超华  马礼  南秋菊 《地域研究与开发》2005,24(4):66-69

退耕还林还草作为北方农牧交错带生态重建的切入点,在实际操作中也不可避免地存在一定的问题。文章对当前退耕还林还草的社会经济特征、政策安排、协调机制及制约因素进行了分析。提出:区域粮食适度自给定位、部门协调机制创新、产权制度改革、区域产业专业化分工、适度生态移民及建立生态补偿机制为进行政策优化调控的主要途径。  相似文献   

合肥盆地早侏罗世防虎山组沉积岩碎屑锆石的矿物包裹体及内部结构   总被引：3，自引：1，他引：3  

陈振宇  周剑雄  李任伟  万渝生 《矿物学报》2005,25(1):89-94

防虎山组的下部砂岩地层是合肥盆地最古老的中生代沉积地层，在样品FH4中选出了碎屑锆石，通过显微激光拉曼光谱、电子探针的研究发现，锆石中含有柯石英、绿辉石、多硅白云母等典型的高压-超高压(HP-UHP)矿物包裹体、熔体玻璃包裹体以及磷灰石、石英、斜长石、白云母等矿物包裹体。结合阴极发光图像所揭示的锆石内部结构的分析以及锆石的微区测年数据，对碎屑锆石的物源进行了讨论。HP-UHP矿物包裹体在具有三叠纪年龄的变质碎屑锆石中的发现，进一步证明大别造山带高压-超高压岩石在早侏罗世时期已经出露地表并为合肥盆地提供了重要物源；碎屑锆石内部结构及成因的多样性表明当时作为源区的大别造山带岩石的复杂性。  相似文献   

Petrogenesis of Cretaceous adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province (eastern China): Implications for geodynamics and Cu–Au mineralization     

Qiang Wang  Derek A. Wyman  Ji-Feng Xu  Zhen-Hua Zhao  Ping Jian  Xiao-Lin Xiong  Zhi-Wei Bao  Chao-Feng Li  Zheng-Hua Bai 《Lithos》2006,89(3-4):424-446

Both adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province, eastern China are associated with Cretaceous Cu–Au mineralization. The Shaxi quartz diorite porphyrites exhibit adakite-like geochemical features, such as light rare earth element (LREE) enrichment, heavy REE (HREE) depletion, high Al₂O₃, MgO, Sr, Sr / Y and La / Yb values, and low Y and Yb contents. They have low ε_Nd(t) values (− 3.46 to − 6.28) and high (⁸⁷Sr / ⁸⁶Sr)_i ratios (0.7051–0.7057). Sensitive High-Resolution Ion Microprobe (SHRIMP) zircon analyses indicate a crystallization age of 136 ± 3 Ma for the adakitic rocks. Most volcanic rocks and the majority of monzonites and syenites in the Luzong area are K-rich (or shoshonitic) and were also produced during the Cretaceous (140–125 Ma). They are enriched in LREE and large-ion lithophile elements, and depleted in Ti, and Nb and Ba and exhibit relatively lower ε_Nd(t) values ranging from − 4.65 to − 7.03 and relatively higher (⁸⁷Sr / ⁸⁶Sr)_i ratios varying between 0.7057 and 0.7062. The shoshonitic and adakitic rocks in the Luzong area have similar Pb isotopic compositions (²⁰⁶Pb / ²⁰⁴Pb = 17.90–18.83, ²⁰⁷Pb / ²⁰⁴Pb = 15.45–15.62 and ²⁰⁸Pb / ²⁰⁴Pb = 38.07–38.80). Geological data from the Luzong area suggest that the Cretaceous igneous rocks are distributed along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China and were likely formed in an extensional setting within the Yangtze Block. The Shaxi adakitic rocks were probably derived by the partial melting of delaminated lower crust at pressures equivalent to crustal thickness of > 50 km (i.e., 1.5 GPa), possibly leaving rutile-bearing eclogitic residue. The shoshonitic magmas, in contrast, originated mainly from an enriched mantle metasomatized by subducted oceanic sediments. They underwent early high-pressure (> 1.5 GPa) fractional crystallization at the boundary between thickened (> 50 km) lower crust and lithospheric mantle and late low-pressure (< 1.5 GPa) fractional crystallization in the shallow (< 50 km) crust. The adakitic and shoshonitic rocks appear to be linked to an intra-continental extensional setting where partial melting of enriched mantle and delaminated lower crust was probably controlled by lithospheric thinning and upwelling of hot asthenosphere along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China. Both the shoshonitic and adakitic magmas were fertile with respect to Cu–Au mineralization.  相似文献